CLIFF
T. JOHNSTON, Ph.D.
Professor
Soil
Chemistry and Mineralogy
Crop,
Soil and Environmental Sciences
Agronomy
Department
1150
Lilly Hall
Purdue
University
West
Lafayette, IN 47907-1150
(765)
496 1716
FAX
(765) 496 2926
e-mail: clays@purdue.edu
Education B.Sc.
University of California, Riverside
(1979) Chemistry
Ph.D. University of California, Riverside (1983)
Soil and Environmental Chemistry.
Prof. Garrison Sposito (Soil Physical Chemistry)
Postdoctoral Fellow.
(1983 - 1985) Los Alamos National
Laboratory, Los Alamos, New Mexico.
Experimental Physical Chemistry - Dr. Basil Swanson and Dr. Irving
Bigio.
Areas of Qualification
·
Surface
chemistry of clay minerals and oxides
·
Clay-organic
reactions
·
Colloid and
Surface Chemistry
·
Molecular
modeling of mineral structures and sorbed species
·
Geochemical
modeling and aqueous chemical speciation.
·
Surface
spectroscopy of oxides and clay minerals
·
Raman
spectroscopy
·
Fourier
transform spectroscopy
·
Nonlinear
optical spectroscopies
·
Nuclear
magnetic resonance
Professional Experience
1979-1982 Graduate Research Assistant,
University of California, Riverside
1982-1983 Regents
Fellow, University of California, Riverside
1983-1985 Postdoctoral Fellow. Los Alamos National Laboratory
1985 Summer
Faculty Fellow. Air Force Office of
Scientific Research
1985-1993 Assistant
Professor, Associate Professor,
Soil and Water Science Department,
University of Florida
1991 Sabbatical
Fellow at Los Alamos National Laboratory
1992 Visiting
Scientist, Katholieke Universiteit Leuven, Belgium
1993-present Associate
Professor, Professor of Soil Chemistry and Mineralogy
Membership in Academic, Professional and
Scholarly Societies
American
Chemical Society
American Association for the Advancement of
Science
Clay Minerals Society
Soil Science Society of Agronomy
Mineralogical Society of America
Awards
and Honors
1982 Graduate
Regents Fellows at the University of California, Riverside
1983 Sigma Xi
1983 Gamma Sigma Delta
1985 Recognized in “Outstanding Young Men in America”
1992 Awarded
K.U. Leuven Visiting Faculty Fellowship (Leuven, Belgium)
1992-95 Associate Editor of Clays and Clay Minerals
1997
Elected as
Councilor for the Clay Minerals Society
1999 General Chair for the 1999 Clay Minerals Society Meetings
1999 Associate Editor for the Soil Science Society of America
Journal (term begins 1 Jan 2000).
2001 Marion L. and Chrystie M. Jackson Award, Clay Minerals Society
PUBLICATIONS
1)
Holtzclaw*,
K. H.; Schaumberg*, G. D.;LeVesque, C.S.; Sposito, G.; Heick, J.A.;
and C.T. Johnston. Analytical properties of the soluble, metal-complexing
fractions in sludge-soil mixtures: V.
Amino acids, hexosamines, and other carbohydrates in fulvic acid, Soil Sci. Soc. Am. J. 44:736-740, 1980.
2)
Sposito*,
G., Holtzclaw, K.H., Johnston, C.T., and LeVesque, C.S. Thermodynamics of sodium-copper exchange on
Wyoming bentonite at 298 K. Soil Sci.
Soc. Am. J. 45:1079-1084, 1981.
3)
Sposito*,
G., Holtzclaw, K.H., LeVesque, C.S.; and Johnston, C.T. Trace metal chemistry
in arid zone field soils amended with sewage sludge: II. Comparative study of
the fulvic acid fraction, Soil Sci. Soc. Am. J. 46:265-275, 1982.
4)
Johnston*,
C.T., Sposito G., Bocian, D. F., and Birge, R.R. A vibrational spectroscopic
study of the interlamellar kaolinite-dimethyl sulfoxide complex. J. Phys. Chem. 88:5959-5964, 1984.
5)
Johnston*,
C.T., and Swanson, B.I. Temperature dependence of the vibrational spectra of
acetanilide: Davydov solitons or Fermi
coupling? Chemical Physics Letters 114:547-552, 1984.
6)
Johnston*,
C.T., G. Sposito, and R. R. Birge. Raman spectroscopic study of kaolinite in
aqueous suspension, Clays and Clay Min.
33:483-489, 1985.
7)
Johnston*,
C.T.; and Sposito*, G. Disorder and early sorrow. Progress in the chemical speciation of the
soil solution. p. 89-100. In Future
developments in soil science research, L.L. Boersma (ed.), Soil Sci. Soc. of
Am. Publications, Madison, WI., 1987.
8)
Scott*,
A.C., Bigio, I.J., and Johnston, C.T.
Polarons in acetanilide.
Physical Review B. B39:12883-12887, 1989.
9)
Johnston*,
C.T., and Stone, D.A. The Influence of hydrazine on the vibrational modes of
kaolinite. Clays and Clay Minerals
38:121-128, 1990.
10)
Johnston*,
C.T., Agnew*, S.F., and D. L. Bish, D.L. Polarized single crystral
FT-IR study of the Keokuk kaolinite and Ouray dickite. Clays and Clay Minerals 38:573-583, 1990.
11)
Johnston*,
C.T. Raman and FT-IR spectra of the kaolinite-hydrazine intercalate. p.
432-454. Chapter 22 In Spectroscopic
characterization of minerals and their surfaces, L.M. Coyne, S.W.S. McKeever,
and D.F. Blake (eds.), Am. Chem. Soc. Books Series #415, Washington, D. C.,
1990.
12)
Johnston*,
C.T., Raman and Fourier transform infrared spectroscopy. Chapter 5 in: Instrumental Surface Analysis
of Geologic Materials. D. L. Perry (ed.) VCH Publishers, New York, NY. pp. 121-155, 1990.
13)
Johnston*,
C.T., Tipton, T., Stone, D.A., Erickson, C., and Trabue, S.L. Vibrational and
electronic spectroscopic study of p-dimethoxybenzene adsorbed on
Cu-montrmorillonite. Langmuir 7:289-296, 1991.
14)
Ince*, E., Johnston*, C.T., and
Moudgil, B.M. FT-IR spectroscopic study of adsorption of oleic acid/oleate on
surfaces of apatite and dolomite. Langmuir 7:1453-1457, 1991.
15)
Johnston*, C.T., Swanson, B.I., and Agnew, S. F.
Low frequency vibrational spectra of crystalline acetanilide at low temperature
and high pressure. J. Phys. Chem. 95:
5281-5286, 1991.
16)
Johnston*,
C.T., Tipton* T., Trabue, S.L., Erickson C.; and Stone, D.A. Vapor
phase sorption of p-xylene on Co- and Cu-exchanged SAz-1 montmorillonite. Environ. Sci. & Technol. 26:382-390,
1992.
17)
Pennell*,
K. D., Rhue* R.D., Rao, P.S.C., Johnston, C.T. Vapor phase sorption
of p-xylene and water on soils and clay minerals. Environ. Sci. &
Technol. 26:756-763, 1992.
18)
Jaynes*,
W. F., Traina, S.F., Bigham, J.M. and Johnston, C.T. Preparation and
characterization of reduced-charge hectorites. Clays and Clay Minerals
40:397-405, 1992.
19)
Johnston*,
C.T., Sposito, G. and Erickson, C.
Vibrational probe studies of water interactions with montmorillonite.
Clays and Clay Miner. 40:722-730, 1992.
20)
Bish*, D. and Johnston*, C.T. Rietveld stuctural refinement of
dickite at 12 K. Clays and Clay
Minerals 41:297-304, 1993.
21)
Tipton*,
T., Johnston*, C.T., Trabue, S.L., Erickson, C.,
Stone, D.A. Gravimetric/FTIR apparatus for the study of vapor sorption on clay
films. Review of Scientific Instruments
64:1091-1092, 1993.
22)
Hinedi*,
Z.H., Johnston *, C.T. and Erickson, C. Chemisorption of benzene on
Cu-montmorillonite as characterized by FTIR and 13C MAS NMR. Clays
and Clay Minerals 41:87-94, 1993.
23)
Johnston*,
C.T.; Sposito, G.; Earl, W.
Characterization of Environmental Particles by Fourier Transform
Infrared and Nuclear Magnetic Resonance Spectroscopy" Chapter 1 in
Environmental Particles Volume 2 in the Environmental
Analytical and Physical Chemistry Series J. Buffle and H. P. van Leeuwen
(eds.) Lewis Publishers, Boca Raton,
FL. pp. 1-36, 1993.
24)
Schulze*,
D. G.; Johnston, C.T., and Bleam, W.F. Visualization of clay mineral
structures. In Clays: Controlling the
Environment. G.J. Churchman, R.W. Fitzpatrick and R.A. Eggleton (eds.) 10th
International Clay Conference Proc., Adelaide Australia. CSIRO Publishing,
Melbourne, Australia, pp. 15-18,
1993.
25)
Johnston*,
C.T.; Davis*, W.; Erickson, C.; and Delfino, J. FTIR Spectroscopic Characterization of
Humic In Substances Humic substances in the global environment and
implications on human health. p. 145-152. N. Senesi and T.M. Miano (ed.), 1994.
26)
Okuda*,
I., Johnston*, C.T. and Rao, P.S.C. Accessibility of solutes to
geometrically rough (fractal) surfaces of natural sorbents. Chemosphere
30:2:389-395, 1995.
27)
Johnston*,
C.T.; and Earl, W. Vibrational and NMR probe studies of water interactions with
homoionic SAz-1 montmorillonite.
Chapter 9 in Metal speciation
and contamination of Soil. H.E. Allen,
C.P. Huang, G.W. Bailey, and A.R. Bowes (eds.)
Lewis Publishers, Boca Raton, FL
p. 237-254., 1995.
28)
Johnston*,
C.T. Sorption of Organic Compounds on
Clay Minerals: A surface functional
group approach. Chapter 1 in Organic
Pollutants in the Environment. B.
Sawhney (ed.) Clay Minerals Society, Boulder Co. pp. 1-44, 1996.
29)
Johnston*,
C.T.; Farmer, W.; and Aochi, Y. Fourier
transform infrared and Raman spectroscopy.
Chapter 10 in: "Methods of Soil Analysis, Part 3. Chemical
Methods, Third Edition," D. Sparks (ed.), Soil Sci. Soc. of Am. Book
Series no. 5., Madison, Wisconsin. p
269-321, 1996.
30)
Madari*,
B., Micheli, E., Johnston*, C.T., Graveel, J.G. and Czinkota I. Long
term effects of tillage on the composition of soil organic matter:
spectroscopic characterization. Agrokem
Es Talajtan 46, 127-134, 1997.
31)
Earl*,
W.; and Johnston*, C.T.
Chemical Speciation of Sorbed Compounds on Environmental Particles using
Nuclear Magnetic Resonance Spectroscopy” Chapter 7 in Environmental Particles
Volume 4 in the Environmental Analytical
and Physical Chemistry Series P.M.
Huang and N. Senesi (eds.) pp. 251-280, 1997.
32)
Johnston*,
C.T., Helsen, J., Schoonheydt, R. and Bish, D.L. Single-crystal Raman
spectroscopic study of dickite.
American Mineralogist, 83:
75-84, 1998.
33)
Bhatti*,
J.S., Comerford*, N.B. and Johnston C.T.
Influence of soil organic matter removal
and pH on oxalate sorption onto a spodic horizon. Soil Sci. Soc. Am. J. 62:152-158, 1998.
34)
Bhatti*,
J.S., Johnston, C.T. and Comerford, N.B. Influence of oxalate and soil organic
matter on sorption and desorption of phosphate onto a Spodic horizon. Soil Sci. Soc. Am. J. 62:1089-1095, 1998.
35)
Robinson*,
S., Johnston, C.T.* and Reddy, K.R. Combined chemical and 31P
NMR spectroscopic analysis of phosphorus in wetland organic soils. Soil Science, 163: 705-713, 1998.
36)
Norton*,
L.D.; Altieri, R.; Johnston, C.T. Co-utilization of by-products for soil
improvement and erosion control. Beneficial Co-utilization of
Agricultural-Municipal and Industrial Byproducts. S. Brown (ed.) Klure Publ,
Dordrecht, Netherlands, pp. 163-174, 1998.
37)
Johnston*,
W. Xu*, P. Parker, S.F. Agnew.
Characterization of active sites on mineral surfaces: A spectroscopic study of water sorption on
montmorillonite. In "The Latest Frontiers of Clay Chemistry. Proceedings of the Sapporo Conference on the
Chemistry of Clays and Clay Minerals (Sapporo, Japan 1996)" A. Yamigishi,
A. Aramata, and M. Taniguchi (eds.)
Publ. Smectite Forum, Sendai Japan. pp. 47-69, 1998.
38)
Nulins*,
K.H.L., H.G. Toufar, G.O.A. Janssens, R.A. Schoonheydt*, and
Johnston, C.T.. 1998. . In "The Latest Frontiers of Clay Chemistry. Proceedings of the Sapporo Conference on the
Chemistry of Clays and Clay Minerals (Sapporo, Japan 1996)" Eds. A.
Yamigishi, A. Aramata, and M. Taniguchi.
Publ. Smectite Forum, Sendai Japan. pp. 116-133, 1998
39)
Madari*,
B., Micheli, E., Czinkota, I., Johnston*, C.T. and Graveel, J.G.
Soil organic matter as indicator of changes in the environment. Anthropogenic influences: Tillage
Agrokem Es Talajtan 47, 121-132, 1998.
40)
Davis*,
W.M., Erickson, C.L., Johnston*, C.T, Delfino, J.J. and Porter,
J.E. Quantitative Fourier Transform
Infrared spectroscopic investigation of humic substance functional group
composition
Chemosphere 38: 2913-2928, 1999.
41) Lin*,
L., Johnston*, C.T., Blatchley E.R.
Inorganic Fouling at Quartz: Water Interfaces in Ultraviolet
Photoreactors I: Chemical Characterization, Water Research 33: 3321-3329, 1999.
42) Lin*,
L., Johnston*, C.T., Blatchley. E.R., Inorganic Fouling at Quartz: Water Interfaces in Ultraviolet
Photoreactors II: Temporal and Spatial Distributions, Water Research 33: 3330-3338, 1999.
43)
Lin*, L., Johnston*, C.T., Blatchley E.R., Inorganic Fouling at Quartz: Water
Interfaces in Ultraviolet Photoreactors III: Numerical Modeling, Water Research
33: 3339-3347, 1999.
44)
Xu*,
W., Johnston*, C.T., Parker, P. and Agnew, S.F. Infrared study of water sorption on Swy-1
and SAz-1 montmorillonite. Clays and
Clay Minerals, 48:120-131, 2000.
45)
Wang*,
S.L., Johnston*, C.T. Assignment of the structural OH stretching
bands of gibbsite. American Mineralogist, 85:739-744, 2000.
46)
Burrell,
L.S.; Johnston, C.T., Schulze, D., Klein, J., White, J.L., Hem, S.L. Aluminum
phosphate adjuvants prepared by precipitation at constant pH. Part I: Composition and structure. Vaccine.
19:275-281, 2000.
47)
Burrell,
L.S.; Johnston, C.T., Schulze, D., Klein, J., White, J.L., Hem, S.L. Aluminum
phosphate adjuvants prepared by precipitation at constant pH. Part II: Physiochemical properties. Vaccine,
19:282-287, 2000.
48)
Johnston*,
C.T.; Eckert, J., Dotson, L., Bish, D.L. Vibrational spectroscopic study of the
1.035 and 0.95 nm kaolinite-hydrazine intercalation complexes. Journal of
Physical Chemistry. 104: (33) 8080-8088, 2000.
49)
Guest*,
C.; Johnston*, C.T.; King, J.; Tishmack, J.K.; and Norton,
L.D.. Synthetic soil from composting
coal combustion byproducts and an industrial biosolid. In Press. Journal
of Environmental Quality.
50)
Johnston*,
C.T.; and Tombacz, E. Surface Chemistry of Soil Minerals. Chapter 2 in "Environmental Soil Mineralogy"
J. Dixon and D. Schulze (eds.) In press.
51)
Goldberg*,
S., Johnston*, C.T. Mechanisms of arsenic adsorption on amorphous
oxides evaluated using macroscopic measurements, vibrational spectroscopy, and
surface complexation modeling. Journal of Colloid and Interface Science. In press.
52)
Johnston*,
C.T. Application of IR and Raman
spectroscopy in Soil and Environmental Science. Handbook of Vibrational Spectroscopy. P.R. Griffiths ed. In
press.